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Creative Empathy

https://doi.org/10.1080/10400419.2023.2229649

Anderson, Stephen ; Cameron, C. Daryl ; Beaty, Roger E. ( July 2023 , Creativity Research Journal)

Free, publicly-accessible full text available July 4, 2024
Light-induced O 2 -dependent aliphatic carbon–carbon (C–C) bond cleavage in bipyridine-ligated Co( ii ) chlorodiketonate complexes

https://doi.org/10.1039/D2DT03727K

Anderson, Stephen N. ; Elsberg, Josiah G. ; Berreau, Lisa M. ( March 2023 , Dalton Transactions)

Illumination of aerobic acetonitrile solutions of bipyridine-ligated Co(ii) chlorodiketonate complexes results in O₂-dependent aliphatic C–C bond cleavage with high¹⁸O incorporation.

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C(sp 3 )–H oxidation and chlorination catalysed by a bioinspired pincer iron( iii ) complex

https://doi.org/10.1039/D2DT02005J

Han, Jian ; Tan, Liming ; Wan, Yanjun ; Li, Gang ; Anderson, Stephen N. ( August 2022 , Dalton Transactions)

A pincer iron(iii) catalyst for the oxidation and chlorination of C(sp³)–H bonds was developed.

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Tris-(2-pyridylmethyl)amine-ligated Cu( ii ) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

https://doi.org/10.1039/d0dt04074f

Elsberg, Josiah G. ; Anderson, Stephen N. ; Tierney, David L. ; Reinheimer, Eric W. ; Berreau, Lisa M. ( February 2021 , Dalton Transactions)
null (Ed.)
We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu( ii ) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C–C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.
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Two-dimensional extreme skin depth engineering for CMOS photonics

https://doi.org/10.1364/JOSAB.416848

van Niekerk, Matthew ; Jahani, Saman ; Bickford, Justin ; Cho, Pak ; Anderson, Stephen ; Leake, Gerald ; Coleman, Daniel ; Fanto, Michael L. ; Tison, Christopher C. ; Howland, Gregory A. ; et al ( March 2021 , Journal of the Optical Society of America B)

Extreme skin depth engineering (e-skid) can be applied to integrated photonics to manipulate the evanescent field of a waveguide. Here we demonstrate thate-skidcan be implemented in two directions in order to deterministically engineer the evanescent wave allowing for dense integration with enhanced functionalities. In particular, by increasing the skin depth, we enable the creation of two-dimensional (2D)e-skiddirectional couplers with large gaps and operational bandwidth. Here we experimentally validate 2De-skidfor integrated photonics in a complementary metal–oxide semiconductor (CMOS) photonics foundry and demonstrate strong coupling with a gap of 1.44 µm.

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